Method of manufacturing a semiconductor device including through silicon plugs

ABSTRACT

A method of making a semiconductor device is provided including forming a first opening and a second opening in a first surface of a substrate. A conductive material is formed in the first opening and in the second opening and over the first surface in the first region of the substrate between the openings. A thickness of the substrate may be reduced from a second surface of the substrate, opposite the first surface, to a third surface opposite the first surface which exposes the conductive material in the first opening and the conductive material in the second opening. A light emitting diode (LED) device is connected to the third surface of the substrate.

CLAIM OF PRIORITY

The present application is a continuation of U.S. application Ser. No.13/942,112, entitled “METHOD OF MANUFACTURING A SEMICONDUCTOR DEVICEINCLUDING THROUGH SILICON PLUGS”, filed on Jul. 15, 2013, which is acontinuation of Ser. No. 12/879,584, entitled “HEAT DISSIPATION BYTHROUGH SILICON PLUGS,” filed on Sep. 10, 2010, now U.S. Pat. No.8,507,940, which claims the priority from U.S. Provisional applicationNo. 61/320,819, entitled “NOVEL SEMICONDUCTOR PACKAGE WITH THROUGHSILICON VIAS,” filed on Apr. 5, 2010, all of which are incorporatedherein by reference in their entireties.

RELATED APPLICATIONS

The present application is related to U.S. application Ser. No.12/329,138, entitled “METHOD FOR PRODUCING STACKABLE DIES,” filed onDec. 5, 2008, which is incorporated herein by reference in its entirety.

BACKGROUND

The trend in advanced semiconductor packaging has been to reduce theform factor while improving electrical performance. This enablesproducts for industry and consumers that are faster, cheaper andsmaller. Through silicon vias (TSVs), or more accurately through siliconplugs (TSPs), provide an approach to achieve higher levels ofintegration and form factor reduction for advanced semiconductorpackaging. As the name implies, the electrical connection of the backand front of a semiconductor device enables the possibility ofvertically assembling multiple chips in a package where previously onlyone chip was present. Accordingly, more semiconductor devices can beintegrated into a smaller form factor. In addition, different types ofsemiconductor chips can also be integrated in a single package to createa so-called system in a package (SIP). Irrespective of the approach, thefootprint of multiple packages in the printed circuit board is reducedwhich also reduces final product cost. Finally, interconnecting thechips by using TSVs can decrease the number of electrical connectionsnecessary to the substrate (i.e., unit), because one substrateconnection can service multiple chips. This also helps to simplify theassembly process and improve yield. In addition, through silicon viasprovide a superior heat dissipation mechanism.

Interest in using light-emitting diodes (LEDs) as lighting devices hassignificantly increased in recent years due to LEDs' high light outputefficiency. However, heat is generated from the PN junctions of LEDs byelectrical energy that is not converted into useful light. If the heatis not removed, the LEDs run at high temperatures, which not only lowertheir efficiency, but also make the LEDs more dangerous and lessreliable. Therefore, thermal management of LEDs is very important.

BRIEF DESCRIPTION OF THE DRAWINGS

The present disclosure will be readily understood by the followingdetailed description in conjunction with the accompanying drawings, andlike reference numerals designate like structural elements.

FIGS. 1A-18 illustrate structures and intermediate stages in a processflow for creating a package for a semiconductor die, in accordance withsome embodiments.

FIGS. 19A-19E show top views of various designs of through silicon plugs(TSPs), in accordance with some embodiments.

FIGS. 20A-20B show top views of two designs of through silicon plugs(TSPs), in accordance with some embodiments.

FIG. 21A shows a top view of a semiconductor chip over a packagesubstrate, in accordance with some embodiments.

FIG. 21B shows a side view of FIG. 12A, in accordance with someembodiments.

FIG. 22 shows the design of FIG. 20B with rounded corners, in accordancewith some embodiments.

FIGS. 23A-24B show various designs of TSPs on package substrates, inaccordance with some embodiments.

FIGS. 25A-25B show a design of TSPs with double-sided combs, inaccordance with some embodiments.

DETAILED DESCRIPTION OF THE EXEMPLARY EMBODIMENTS

It is to be understood that the following disclosure provides manydifferent embodiments, or examples, for implementing different featuresof the present disclosure. Specific examples of components andarrangements are described below to simplify the present disclosure.These are, of course, merely examples and are not intended to belimiting. In addition, the present disclosure may repeat referencenumerals and/or letters in the various examples. This repetition is forthe purpose of simplicity and clarity and does not in itself dictate arelationship between the various embodiments and/or configurationsdiscussed.

FIGS. 1A-18 show cross-sectional views of intermediate stages in themaking of some embodiments of this disclosure. FIG. 1A shows a firstsubstrate 100 with a photoresist pattern, in accordance with someembodiments of this disclosure. The first substrate 100 may comprise,for example, bulk silicon, doped or undoped, or an active layer of asemiconductor-on-insulator (SOI) substrate. Generally an SOI substratecomprises a layer of a semiconductor material, such as silicon, formedon an insulator layer. The insulator layer may be, for example, a buriedoxide (BOX) layer or a silicon oxide layer. The insulator layer isprovided on a substrate, typically a silicon or glass substrate. Othersubstances, such as multi-layered or gradient substrates may also beused.

In the example described here, the first substrate 100 is made of asilicon material 140. There is a dielectric layer 101 deposited over thesilicon material 140. A photoresist layer 102 is then deposited over thedielectric layer 101 and the photoresist layer 102 is patterned withopenings, such as openings of through silicon vias. The dielectric layer101 is a sacrificial layer used to protect substrate surface during theetching process of through silicon vias.

In some embodiments, the first substrate 100 already has an electricalcircuitry 190 built in, as shown in FIG. 1B, before the photoresistlayer 102 is deposited and patterned. FIG. 1B shows that the electricalcircuitry 190 has been formed on the first substrate 100. The electricalcircuitry 190 may be any type of circuitry suitable for a particularapplication. In an embodiment, the circuitry includes electrical devicesformed on the substrate with one or more dielectric layers overlying theelectrical devices. Metal layers may be formed between dielectric layersto route electrical signals between the electrical devices. Electricaldevices may also be formed in one or more dielectric layers.

For example, the electrical circuitry 190 may include various N-typemetal-oxide semiconductor (NMOS) and/or P-type metal-oxide semiconductor(PMOS) devices, such as transistors, capacitors, resistors, diodes,photo-diodes, fuses, and the like, interconnected to perform one or morefunctions. The functions may include memory structures, processingstructures, sensors, amplifiers, power distribution, input/outputcircuitry, or the like. One of ordinary skill in the art will appreciatethat the above examples are provided for illustrative purposes only tofurther explain applications of the present disclosure and are not meantto limit the present disclosure in any manner. Other circuitry may beused as appropriate for a given application.

Also shown in FIG. 1B are an etch stop layer 191 and an inter-layerdielectric (ILD) layer 192. In some embodiments, the etch stop layer 191is preferably formed of a dielectric material having a different etchselectivity from adjacent layers, e.g., the underlying first substrate110 and the overlying ILD layer 192. In an embodiment, the etch stoplayer 191 may be formed of SiN, SiCN, SiCO, CN, combinations thereof, orthe like deposited by chemical vapor deposition (CVD) or plasma-enhancedCVD (PECVD) techniques.

The ILD layer 192 may be formed, for example, of a low-K dielectricmaterial, such as silicon oxide, phosphosilicate glass (PSG),borophosphosilicate glass (BPSG), fluorinated silicate glass (FSG),SiO_(x)C_(y), Spin-On-Glass, Spin-On-Polymers, silicon carbon material,compounds thereof, composites thereof, combinations thereof or the like,by any suitable method, such as spinning, CVD, and PECVD. It should alsobe noted that the etch stop layer 191 and the ILD layer 192 may eachcomprise a plurality of dielectric layers, with or without an etch stoplayer formed between adjacent dielectric layers.

Contacts 195 are formed through the ILD layer 192 to provide anelectrical contact to the electrical circuitry 190. The contacts 195 maybe formed, for example, by using photolithography techniques to depositand pattern a photoresist material on the ILD layer 192 to exposeportions of the ILD layer 192 that are to become the contacts 195. Anetch process, such as an anisotropic dry etch process, may be used tocreate openings in the ILD layer 192. The openings are, preferably,lined with a diffusion barrier layer and/or an adhesion layer (notshown), and filled with a conductive material. Preferably, the diffusionbarrier layer comprises one or more layers of TaN, Ta, TiN, Ti, CoW, orthe like, and the conductive material comprises copper, tungsten,aluminum, silver, and combinations thereof, or the like, thereby formingthe contacts 195 as illustrated in FIG. 1B.

FIG. 2 shows first substrate 100 after the openings have been etched, inaccordance with some embodiments. Although FIG. 2 does not show theelectrical circuitry 190, contact plugs 195, and dielectric layers 191and 192 of FIG. 1B, such features can exist in FIG. 2 and the figuresfollowing FIG. 2. In an embodiment, a timed etching process, such as ananisotropic dry etch process, is performed until a desired depth for theopenings 110 is obtained in the first substrate 100. It should beunderstood that the etch processes described herein may be accomplishedin single etch processes or multiple etch processes. The etchingprocess(es) can be a dry process or a wet process.

In some embodiments, the depths of openings may range from about 20 μmto about 200 μm. In some embodiments, the widths of openings may rangefrom about 5 μm to about 100 μm. In some embodiments, the openings 110are through silicon vias (or trenches). Etching openings with suchdepths by purely relying on the photoresist layer 102 could be hamperedby the physical limitations of the process. In the embodiments shownhere, the dielectric layer 101 is first etched and then used as apatterning mask. The material for the dielectric layer 101 can be anydielectric material, such as silicon dioxide, silicon nitride, or acombination of both films. One example of a material for the dielectriclayer 101 is silicon oxide deposited by plasma enhanced chemical vapordeposition (PECVD) using TEOS (Tetraethyl orthosilicate) as the siliconsource. PECVD silane oxide film can also be used. In some embodiments,the TEOS oxide has a thickness between about 500 Å to about 10000 Å. Thedielectric layer 101 does not need to be deposited by PECVD. Thedielectric layer 101 can be a spin-on dielectric (SOD) or a spin-onglass (SOG). The dielectric layer 101 can also be deposited (or grown)by a thermal process, such as a thermally grown silicon dioxide, or anoxide film deposited by thermal CVD.

After the through silicon vias have been etched, the photoresist and thesacrificial dielectric layer 101 are both removed. After the openings,such as opening 110, are created, the openings are filled. FIG. 3 showsthat the substrate is first lined with an isolation layer 103 and abarrier/Cu-seed layer 104, in accordance with some embodiments. Theisolation layer 103 is made of a dielectric material, such as oxide,nitride, or a combination of both. One example of a material for theisolation layer 101 is silicon oxide deposited by plasma enhancedchemical vapor deposition (PECVD) using silane or TEOS as the siliconsource. In some embodiments, the isolation layer has a thickness betweenabout 500 Å to about 15000 Å. The isolation layer 103 can also bedeposited (or grown) by a thermal process, such as a thermally grownoxide, or a thermal CVD oxide. Alternatively, the dielectric isolationlayer 103 can be a doped film, using dopants such as phosphorus (P) orboron (B) and phosphorus (P). The phosphorus (P) in the PSG (phosphorussilicon glass) or BPSG (boron phosphorus silicon glass) film can gettercopper, which is used to fill the openings, which are through siliconvias (or trenches) in this example. Copper can diffuse into the siliconsubstrate. Although the through silicon vias are lined with a barrierlayer, which will be described later, the barrier coverage could beinsufficient on the sidewalls near the bottom of the vias, such as atcorner 170. Using PSG or BPSG as the isolation layer 103 can provideextra protection against copper diffusion.

Dielectric layer 103 has higher thermal resistance than silicon. Table Icompares the simulation results for the thermal resistance of siliconsubstrate with an oxide dielectric layer of varying thicknesses.

TABLE I Comparison of thermal resistance for various silicon/oxidethicknesses. Si/Oxide Thermal Resistance (μm/μm) (K/Watt) 100/0  1.81100/1.5 6.37 50/0  0.92  50/1.5 5.95The data in Table I show that oxide could significantly increase thethermal resistance. Therefore, the thickness of dielectric layers in thepackage should be kept to a minimum.

After the isolation layer 103 is deposited, a barrier/Cu-seed layer 104is deposited. The barrier/Cu-seed layer 104 includes at least twosub-layers, a barrier layer and a copper seed layer. The barrier layeris made of one or more copper barrier materials, such as Ta, TaN, Ti,TiN, CoW, or the like. The barrier layer provides protection againstcopper diffusing into the silicon substrate 100. The barrier layer canbe deposited by PVD (physical vapor deposition), chemical vapordeposition (CVD), atomic layer deposition (ALD), or other methods. Afterthe deposition of the barrier layer, a copper seed layer is deposited.Similarly, the copper seed layer can be deposited by PVD (physical vapordeposition), chemical vapor deposition (CVD), atomic layer deposition(ALD), or other methods. In some embodiments, the barrier/Cu-seed layer104 is made of TaN/Ta barrier and a copper seed layer. The barrier layer104 in this embodiment is made of two sub layers, a TaN layer and a Talayer. In some embodiments, TaN, Ta and Cu seed are all deposited byPVD, and the deposition of TaN, Ta, and Cu seed are all conducted in onesingle PVD chamber with different targets and sputtering gases. In someembodiments, each thickness of TaN and Ta is between about 100 Å toabout 2000 Å, and the thickness of the copper seed layer is betweenabout 1000 Å to about 15000 Å.

After the deposition of the barrier/copper-seed layer 104, the substrateis patterned to define areas to receive copper plating. FIG. 4 shows apatterned photoresist layer 105 being formed on the first substrate 100,in accordance with some embodiments. In some embodiments, the patternedphoto-layer 105 is made of conventional photoresist, which is in liquidform and is deposited by a spin-on process. In another embodiment, thematerial of the patterned photo-layer 105 is a dry film resist (DFR),which can also be patterned by photolithography (i.e., with lightexposure). The DFR can be a positive or a negative photoresist. DFR hasbeen used for creating patterns for copper plating for circuit boards.An example of DFR is MP112, made by TOK CO. LTD. of Japan. After the DFRis laminated on the first substrate 100 (or over layer 104), the DFR isexposed with a pattern that defines areas on the substrate surface thatwould receive copper plating. Using dry film resist has an advantageover the wet spin-on photoresist in that the dry film resist is onlylaminated on the substrate surface. In contrast, wet spin-on photoresistwould flow into the openings, such as opening 110. Since the openingsfor through silicon vias (or trenches) are quite deep, as mentionedabove between about 20 μm to about 200 μm, the wet photoresist filledinside could be hard to removed completely for copper to be properlyplated on the sidewalls and bottom surfaces of the openings.

FIG. 5 shows a copper film 106 being plated on the first substrate 100and the DRF being stripped from the substrate surface after copperplating, in accordance with some embodiments. Electrical copper plating(ECP) processes or electroless copper plating process used in the metalinterconnects of semiconductor device manufacturing can be used. In someembodiments, the thickness of the copper film 106 is less than about 30μm. In other embodiments, the thickness of the copper film 106 is lessthan about 20 μm. In yet some other embodiments, the thickness of thecopper film 106 is less than about 10 μm. A copper film that is toothick could result in substrate warping. In some embodiments, the copperfilm 106 is deposited to only fill the openings (or through siliconvias), such as opening 110 shown in FIG. 4. In another embodiment, thecopper film 106 is deposited not only to fill the (through silicon via)openings, but also to provide landing pads for packaged devices on asubstrate, such as a PCB (printed circuit board), or to receivesemiconductor chips.

In some embodiments, the thickness of film 106 is between about 10 μm toabout 30 μm. After copper film 106 is plated, the photo-layer 105 isremoved. Both wet spin-on photoresist and dry film resist can be removedby an ashing process, which is typically followed by a wet clean tocompletely remove the impurities on the substrate surface.

After copper plating and resist removal, the barrier/Cu-seed layer 104in the areas that do not receive copper plating is removed, as shown inFIG. 6 in accordance with some embodiments. Following the previousoperation, the front of the substrate is glued to a second substrate 108as shown in FIG. 7. The second substrate 108 is a dummy substrate andcan be made of a dielectric material, such as glass. Alternatively, thesecond substrate 108 can be made of a conductive material, such asmetal. FIG. 7 shows that substrate 100 is glued to the second substrate108 with a glue layer 107, in accordance with some embodiments. Thematerial used for the glue layer 107 should allow for easy removal whenthe dummy substrate 108 is no longer needed. In some embodiments, thematerial for the glue layer 107 is an epoxy polymer. The glue layer 107is first applied on the first substrate 100 in liquid form. After thesecond substrate 108 is placed over the glue layer 107, the glue layercan be left to dry or be heated at a low temperature. After drying andheating (or curing), substrate 100 is firmly attached to dummy substrate108.

Afterwards, first substrate 100 undergoes backside grinding to removeexcess silicon to expose the through silicon vias 120. In someembodiments, backside grinding is followed by chemical mechanicalpolishing (CMP) processing to smooth the substrate surface that hasundergone grinding. FIG. 8 shows the first substrate 100 after thebackside silicon has been removed to expose the through silicon vias120, in accordance with some embodiments. In some embodiments, thesilicon removal process is a grinding process. A grinding wheel iscommonly used in packaging processes to remove excess silicon fromsilicon substrate. The grinding is performed until the isolation layer103 and barrier/Cu-seed layer 104 are completely removed from thebottoms of through silicon vias 120.

Reducing the thickness of silicon substrate can improve heat dissipationefficiency of silicon substrate. Table II compares the simulationresults for the thermal resistance of silicon substrates with varyingthicknesses.

TABLE II Comparison of thermal resistance for silicon substrates withvarying thicknesses. Thickness Thermal Resistance (μm) (K/Watt) 500 4.82200 3.18 100 1.81 50 0.92The data show that the thermal resistance is greatly reduced when thesubstrate thickness is reduced to 100 μm. The thinner silicon thicknessprovides extra heat dissipation in addition to the heat dissipationprovided by the copper in the through silicon vias (or trenches).

After backside grinding, the backside of first substrate 100 isdeposited with a dielectric layer 150, as shown in FIG. 9 in accordancewith some embodiments. Similar to isolation layer 103, dielectric layer150 can be made of oxide, nitride, or a combination of both. One exampleof a material for the dielectric layer 150 is silicon oxide deposited byplasma enhanced chemical vapor deposition (PECVD) using silane as thesilicon source. In some embodiments, the isolation layer has a thicknessbetween about 5000 Å to about 20000 Å. In some embodiments, thedielectric layer 150 is a doped film, using dopants such as phosphorus(P) or boron (B) and phosphorus (P). As mentioned above, the phosphorus(P) in the PSG or BPSG film can getter copper.

Following the deposition of dielectric layer 150, the substrate isdeposited and patterned with a photoresist layer 151, as shown in FIG.10 in accordance with some embodiments. The photoresist layer 151 can bedeposited with a spin-on resist (wet) or a dry film resist. The patternopens at the areas of through contact vias (or trenches) in order toremove the dielectric layer 150 of those areas. After the photoresistpattern is formed, the dielectric layer 150 exposed by the pattern isremoved by etching. Dielectric etching processes used in semiconductorchip manufacturing can be used to achieve the removal purpose. Theetching processes can be dry processes or wet processes. FIG. 11 showsthe first substrate 100 and the second substrate 108 after thedielectric layer 150 in the open areas is etched, in accordance withsome embodiments.

Afterwards, a barrier/Cu-seed layer 152 is deposited as shown in FIG.12, in accordance with some embodiments. The barrier/Cu-seed is acomposite layer of a barrier layer and a copper seed layer. The barrierlayer protects the Si substrate from diffused copper. As mentionedabove, Ta, TaN, Ti, TiN, CoW, or a combination of the above-mentionedfilms can be used as barrier. In some embodiments, the barrier materialis Ti and a thickness between about 500 Å to about 5000 Å is deposited.A thin copper seed layer is deposited with a thickness between about1000 Å to about 10000 Å. The deposition methods that can be used todeposit the barrier layer and copper seed layer have been mentionedabove.

After the deposition of the barrier/Cu-seed layer 152, the substrate ispatterned with a photoresist layer 153 to define regions receivingcopper plating, as shown in FIG. 13 in accordance with some embodiments.As mentioned above, the photoresist can be a spin-on resist (wet) or aDFR. After resist patterning, a copper layer 154 is first plated on theexposed areas (not covered by the photoresist) of the substrate. Asmentioned above, the plating process for copper layer 154 can be anelectrical chemical plating process (ECP) or an electroless copperplating process. In some embodiments, the thickness of the copper layer154 is less than 30 μm due to concern of substrate warping describedabove. In some embodiments, the thickness of copper layer 154 is betweenabout 10 μm to about 20 μm. Afterwards, a diffusion barrier layer 155 isdeposited over layer 154. The diffusion barrier layer 155 willeventually receive a solder layer and one or more integrated circuit(IC) chips (to be described below). The diffusion barrier layer 155prevents copper from layer 154 from diffusing into the IC chips disposedabove the TSV substrate. In some embodiments, the diffusion barrierlayer 155 is also deposited by plating, such as ECP or electrolessplating. In some embodiments, the diffusion barrier layer 155 is made ofnickel immersion gold (ENIG). However, any appropriate diffusion barriermaterial may be used.

After the deposition of the diffusion barrier layer 155, the photoresistlayer 153 and the barrier/Cu-seed layer 152 underneath the photoresistlayer 153 are removed. FIG. 14 shows substrate 100 without thephotoresist layer 153 and the barrier/Cu-seed layer 152 underneath, inaccordance with some embodiments. At this point, the first substrate 100is prepared to receive the semiconductor chip. Different semiconductorchips could be mounted on the first substrate 100 with slightlydifferent process flows. In some embodiments, the semiconductor chipsare light emitting diodes (LEDs) or similar light-emitting devices.

Following the previous operation, a semiconductor chip 156 is secured tothe diffusion barrier layer 155 with the help of a eutectic bondinglayer 157. In some embodiments, the eutectic bonding layer 157 is madeof solder. In the embodiment shown in FIG. 15, the semiconductor chip156 is a light-emitting diode (LED). The LED chip is placed on P-contact159, and the LED chip is electrically connected to the N-contact 160 viaa wire 158. A wire bonding operation is performed to connect the LEDchip 156 to the N-contact 160. FIG. 15 shows the LED chip 156 beingplaced on the first substrate 100 and bonded to the substrate 100 by theeutectic bonding layer 157 and also being bonded to the N-contact via awire 158, in accordance with some embodiments. The LED chip 156 isdirectly placed on the first substrate 100 without a conductive bumpbecause the surface of layer 155 of P-contact 159 is relatively planar.

The copper layer 154 of FIGS. 13-15 provides electrical connection andthermal contact to the semiconductor chip (such as an LED chip) 156placed on top. The copper layer 154 can also be referred to as a metalpad and does not need to be made of copper. In some embodiments, themetal pad (154) can be made of solder, which can be deposited by aplating process (as described above) or by applying a solder paste overthe substrate surface after the photoresist layer 153 is patterned. Thesolder paste would fill in the openings created by the photoresist layer153 and leaves very little amount over the photoresist layer 153. Thesmall amount of solder paste over the photoresist layer 153 would havelittle effect on the removal process of the photoresist layer 153. Ifsolder is used for layer 154 (as a metal pad), the copper seed layerportion of barrier/Cu-seed layer 152 is not needed, in accordance withsome embodiments. If the solder layer is plated, a solder seed layer ora seed layer made of non-solder material can be used. However, if thesolder layer is pasted on the substrate, a seed layer is not needed.

As shown in FIG. 15, portions of TSVs 120 and layer (or metal pad) 154extend beyond the edges of the LED chip 156. The extension of electricaland/or thermal connections (such as TSVS 120 and layer 154) of a packagesubstrate (such as substrate 100) beyond the boundary of thesemiconductor chip (such as LED 156) can be called fan-out packaging,which provide extra additional area for re-routing and for heatdissipation. The extension of metal layer 154 beyond the edges of LEDchip 156 provides horizontal pathways and areas for heat dissipation.The extension of TSVs 120 beyond the edges of LED chip 156 provides roomfor additional TSVs 120 to provide vertical paths and areas for heatdissipation. Both the horizontal and vertical pathways and areas affectand improve the efficiency of heat dissipation.

After the LED chip 156 is bonded to the substrate and wire bonded, theLED chip 156 is packaged, as shown in FIG. 16 in accordance with someembodiments. In some embodiments, a layer of phosphorus film 161 isdeposited on the LED chip 156. An LED chip is designed to emit red,blue, or green light. LED chips emitting red, blue and green light areoften placed together in order to create white light. Phosphorous filmcan also be used to generate white light. In some embodiments, thephosphorus film 161 is coated on the LED chip 156. However, coating ofthe phosphorous film 161 is optional. In some embodiments, differentphosphorus films are coated on LEDs with different colors (or differentemitted wavelengths). In some other embodiments, a phosphorous film,such as film 161, is not needed.

Afterwards, a molding material 162 is deposited to surround the LED chip156, the P-contact 159, and the N-contact 160. In some embodiments, themolding is made of a transparent epoxy resin. Transparent moldingmaterial is relevant to LEDs. If the semiconductor chip is not an LED,the molding does not need to be transparent.

FIG. 17 shows the side of molded LED chip 156 is placed on an adhesivetape 163, in accordance with some embodiments. The adhesive tape(sometimes called blue tape) 163 securely supports the molding 162 ofthe LED chip 156 and the first substrate 100 in preparation of detaching(or debonding) the second substrate 108. After the second substrate 108and the glue layer 107 are chemically and mechanically removed, thefirst substrate 100 is sawed to physically separate dies on the firstsubstrate 100, with each die having an LED chip 156, N-contact 160 andP-contact 159. FIG. 18 shows the dummy substrate 108 and glue layer 107having been removed and the adhesive tape 163 holding a single packagedchip 180, in accordance with some embodiments. Other processingoperations, such as placing packaged chip 180 on a PCB, removingadhesive tape layer 163 etc., may follow afterwards.

The exemplary process flow described above shows how semiconductor chipscould be packaged with a substrate with through silicon vias to improveheat dissipation. Further, the heat dissipation of the packaged chipdescribed above is superior to other through silicon via technologiesbecause the thickness of the silicon substrate has been thinned tobetween about 20 μm to about 200 μm.

As mentioned above, the chip packaging method and structures describedabove can be used for semiconductor chips that are not LEDs. When thepackaging methods and structures are used for non-LED chips, the processflows could be different in some portions, especially the processoperations after an LED is used (i.e., after FIG. 15).

Through silicon plugs (or vias, or trenches) under the semiconductorchips could be in various shapes and dimensions. For example, thethrough silicon vias can be in the shape of cylinders. FIG. 19A shows atop view of a TSP (or TSV) 401 (a cylinder), in accordance with someembodiments. The diameter of the TSP 401 is D1. As mentioned above, D1may be in the range between about 5 μm to about 100 μm. For small chipswith about the same surface areas (or top surface areas) as the surfaceof TSP 401, a single TSP, such as TSP 401, can be used. However, oftenthe semiconductor chips have surface area (or top surface area) muchlarger than the surface area of a single TSP. For example, the surfacearea of an LED chip can be 0.6×0.6 mm², 1×1 mm², or larger. Thesenumbers are merely exemplary. In addition, the top surface of thesemiconductor chip does not have to be in square shape. The top surfacecan be in rectangular shape or in other shapes.

A TSP cannot be made too large (or with a cross section that is toolarge) to avoid extensive gap-filling time and other issues. FIG. 19Bshows an embodiment of TSPs (or TSVs) with multiple TSPs, such as 402,403, 404, and 405, to provide thermal dissipation for the semiconductorchip disposed over the TSPs. FIG. 19B only shows 4 TSPs. However, therecould be more than 4 TSPs or less than 4 TSPs (such as 2 or 3). In someembodiments, the diameter D2 for each TSP in FIG. 19B is between about 5μm to about 100 μm. D3 is the smallest distance between two TSPs in FIG.19B. In some embodiments, D3 is equal to or larger than D2. Sufficientdistance is needed between the neighboring TSPs to ensure goodelectrical isolation and to provide structural strength. As mentionedabove in the process flow, the substrate undergoes mechanicalprocess(es), such as backside grinding and sometimes chemical-mechanicalpolishing, which exerts large amounts of stress on the substrate.Without sufficient structural support of the dielectric layer betweenTSPs, the substrate can crack and/or the substrate layers with the TSPscan crack or pill.

In some embodiments, the TSPs (or TSVs) can be in the configuration ofconcentric rings with a central cylinder, as shown in FIG. 19C. Therecould be one or more concentric rings. FIG. 19C shows one concentricring 407, surrounding a central cylinder 406. In some embodiments, thediameters D4 for TSV 406 and width D6 of TSP 407 are between about 5 μmto about 100 μm. In some embodiments, the distance between the TSPs, D5,is equal to or larger than either D4 or D6. As mentioned above,sufficient support from the insulating layer(s) is needed.

TSPs do not need to be in circular shapes. They can be in other types ofshapes, such as triangular, square, rectangular, oval, hexagonal, etc.FIG. 19D shows a number of rectangular TSPs, such as TSPs 408 and 409,in accordance with some embodiments. The rectangular TSPs (or throughsilicon trenches) 408 and 409 both have a width L1 and with a length L2,and are separated by a distance L3. In some embodiments, the width L1 isbetween about 5 μm to about 100 μm. In some embodiments, the distancebetween the TSPs, L3, is equal to or larger than L1. The number ofrectangular-shaped TSPs could be one or more.

In some embodiments, the TSPs could be a pattern, as shown in FIG. 19E.FIG. 19E shows that a patterned TSP 410 having a number of openings,such as opening 411, inside the pattern. The openings 411 in FIG. 19Eare square-shaped (cross-section). However, the openings can berectangular columns, circular cylinders, or other shapes of columns. Insome embodiments, the distance between the openings 411 is L5, which isequal to or smaller than the width of the opening L4.

FIGS. 20A and 20B show two other different configurations of TSPs, inaccordance with some embodiments. The configurations in FIGS. 20A and20B are similar, in some embodiments. The TSPs in FIGS. 20A and 20B areshaped liked doubled-sided combs. The double-sided combs of TSPs in FIG.20B are longer than the combs TSPs of FIG. 20A. The widths of TSPs inFIGS. 20A and 20B are both L6, which is between about 5 μm to about 100μm in some embodiments. The spaces L7, L8 and L9 between combs in FIGS.20A and 20B are equal to or greater than L6, and also between about 5 μmto about 100 μm in some embodiments. The width and height of one of theTSP structures in FIG. 20A, such as structure A1, are W1 (width) and H1(height) respectively. The width and height together with the spacesbetween structures of structure A1 of FIG. 20A are W1′ and H1′respectively. The width and height of the one of the TSP structure inFIG. 20B, such as structure B1, are W2 (width) and H2 (height)respectively. The width together with the space between structures ofstructure A1 of FIG. 20A is W2′. The number of combs on one side ofstructure A1 is 3. However, the number can be any number, such as 1, 2,. . . to N. N is an integer number, which can be 10 or higher. Thenumber of combs on one side of structure B1 is as high as needed toexpand the entire width or length of a semiconductor chip, such as anLED chip 156, placed over the TSP substrate, such as substrate 100. Insome embodiments, the A1 or B1 TSP structures of FIGS. 20A and 20B arerepeated to cover the entire width and length of the semiconductor chip.In some embodiments, the A1 or B1 TSP structures of FIGS. 20A and 20Bare repeated to cover the entire width and length of the semiconductorchip and extends beyond the entire width and length of the semiconductorchip (i.e. TSP area of package substrate is larger than thesemiconductor chip). The width and height of TSP structures can bedesigned to be best suited to the semiconductor chips to providesufficient heat dissipation.

The TSPs 412 of FIG. 20A and TSPs 413 of FIG. 20B have patterns thatallow large cross-sectional areas of TSPs. Yet the TSPs of FIGS. 20A and20B are not made of one large TSP, such as TSP 401 of FIG. 19A. Suchpatterns prevent manufacturing issues, such as long plating time, weakstructural support and others. The large cross-sectional areas providelarge amount of heat transfer pathways and areas. As mentioned above,some semiconductor chips, such as LED chips, generate a large amount ofheat that needs to be dissipated. A substrate with large cross-sectionalareas of TSPs is useful in providing a large amount of heat transferpathways. Duty ratio is used to quantify the amount of heat dissipationpathways of a package with TSPs. Duty ratio is defined as conductiveareas (cross-sections of TSPs) divided by the total chip (placed abovethe conductive areas, such as an LED chip) cross-sectional area, asshown below in equation (1).

Duty Ratio=Conductive Areas/Total Chip Cross-Sectional Area  Eq. (1)

A semiconductor package (or substrate) with a high duty ratio canprovide a higher rate of heat dissipation compared to a package with alower duty ratio. The embodiments of TSP configurations in FIGS. 20A and20B show 4 separate TSP structures A1, A2, A3, A4 in FIG. 20A and 2separate TSP structures B1, B2 in FIG. 20B. If the widths and spaces ofTSP combs are the same in FIGS. 20A and 20B, the TSP configuration inFIG. 20B has a higher duty ratio than the configuration in FIG. 20A. Theconfiguration in FIG. 20A has additional spaces between structures A1and A3 and between structures A2 and A4, in comparison to theconfiguration in FIG. 20B. Therefore, the duty ratio of theconfiguration in FIG. 20A is lower than that of FIG. 20B. If the widthsand spaces of TSP combs in FIG. 20B are the same (L6=L7=L9), thepercentage of TSPs cross-sectional areas to the total cross-sectionalarea can be 50% or higher. If the TSP structures extend beyond the edgesof the semiconductor chip (fan-out packaging), the duty ratio would begreater than 50%.

FIG. 21A shows a top view of a semiconductor chip 450 placed on top of apackage substrate 460, in accordance with some embodiments. The TSPstructures of the package substrate 460 extend beyond the width andlength of semiconductor chip 450. The duty ratio of the packaged chip asshown in FIG. 21A is greater than 50%. FIG. 21A also shows a number ofTSPs 463 that are part of an N-contact, if the semiconductor chip 450 isan LED chip, in accordance with some embodiments. Under thiscircumstance, the LED chip 450 is placed on a P-contact and is wired tothe N-contact through a wire 462, in some embodiments.

As described above, there could be a metal layer, such as layer 154 ofFIGS. 15-18, which provide connection between the semiconductor chip andthe TSP structures. The extended area 465 of the metal layer outside thesemiconductor chip 450 provides lateral heat dissipation pathways forthe semiconductor chip 450. FIG. 21B shows a side view of FIG. 21A cutalong line OO. The TSPs of substrate 460 provides vertical heatdissipation pathways.

The TSP structures in FIGS. 19D and 19E, and FIGS. 20A and 20B all haverigid corners. During substrate processing, the patterning process canmake the corners rounded. FIG. 22 shows structure B1 of FIG. 20B withcorners rounded. The rounded B1 structure in FIG. 22 is formed byplacing two unit structures C1, as shown in FIG. 23A, together, inaccordance with some embodiments. In some embodiments, the length H ofthe unit structure C1 is about 150 μm and the width is about 125 μm. Thewidth and space of TSP structures in C1 are both about 25 μm, in someembodiments. For a semiconductor chip, such as an LED chip, that isabout 0.6 mm by about 0.6 mm (or 0.6×0.6 mm²), 16 C1 structures can beput together in a 4×4 fashion to fill the area under the semiconductorchip. The width of the C1 unit is about 125 μm, because, there is aspace about 25 μm between two C1 units. FIG. 23B shows 16 C1 structuresfill an area of 0.6 mm×0.6 mm of a package substrate to dissipate heatfor a semiconductor chip that is about 0.6×0.6 mm². Between the C1structures, there are spaces, which have a width about 25 μm.

FIG. 23C shows a C2 structure, which is similar to the C1 structure ofFIG. 23A, whose length is about 300 μm and the width is about 250 μm inaccordance with some embodiments. The width and space of TSP structuresin C2 are both about 50 μm, in some embodiments. Four C2 structures canbe used to fill an area about 0.6×0.6 mm2. FIG. 23D shows thearrangement of 4 C2 unit structures. Between the C2 structures, thereare spaces, which have a width about 50 μm. In some embodiments, each ofthe double-sided combs, such as structures C1, C2, and C3, has a widthof between about 100 μm to about 300 μm. In some embodiments, each ofthe double-sided combs, such as structures C1, C2, and C3, has a lengthof between about 100 μm to about 300 μm.

For semiconductor chips that are larger, additional TSP unit structurescan be added into the design of TSP configuration (or structures) toprovide high duty ratio for heat dissipation. In some embodiments, thesemiconductor chip has a dimension of about 1×1 mm². For suchsemiconductor chips, an arrangement of 7×7 C1 chips would cover most ofthe areas under the chip, as shown in FIG. 23E, in some embodiments. Inother embodiments, 4×3 C2 chips can cover the majority of area under a1×1 mm² chip. FIG. 23F shows 4×3 C2 TSP units arranged on a substrate460′, which is under a 1×1 mm² semiconductor chip 450′. In addition tothe exemplary unit structures shown in FIGS. 23A and 23C, otherstructures are also possible. FIG. 24A shows a TSP unit structure C3,which is similar to structure C1 and structure C2, in accordance withsome embodiments. Unit structure has a height of about 120 μm and awidth of about 100 μm. The width and space of the comb structures areboth about 20 μm. In some embodiments, 9×9 of C3 TSP structures aredesigned in the package substrate to cover the entire surface area of a1×1 mm² semiconductor chip. FIG. 24B shows the arrangement of the C3structures of a package substrate 460″ and the 1×1 mm² semiconductorchip, in accordance with some embodiments.

The doubled-sized-comb structures of TSPs described above in FIGS. 20A,20B, 21A, 23B, 23D, 23E, 23F, and 24B are all placed side by sized withtips of combs pointing to one another. In some embodiments, the tips ofcombs can be staggered, as shown in FIG. 25A. Comb D1 and comb D2 ofFIG. 25A have their tips not pointed directly to one another. Instead,combs D1 and D2 are staggered and tips are off-set from one another.Region P of FIG. 25A is expanded in FIG. 25B, which shows that tip T1 ofcomb D1 is not in the same horizontal line with tip T2 of comb D2. Asmentioned above the first width D3 of the combs is about equal to thesecond width D4 of combs, in some embodiments. As described above, inFIGS. 20A, 20B, 23A, 23B, 23C, 23D, 23E, 23F, 24A, and 24B, the space D5between two separate combs is roughly equal to the widths D3, D4, of thecombs, in some embodiments. Sufficient spacing between combs providesstructural support for the TSPs. However, due to the staggered nature ofcombs D1 and D2, the distance between two neighboring and separate combsis D6, which is about 1.41×D5. If D6=D3=D4, D5 can be smaller than D3and D4 and can be about 0.71×D3 (or D4). With a smaller D5 (than D3 orD4), the combs can be packed tighter. The reduced spacing betweenindependent and neighboring combs can increase the duty ratios ofpackage substrates.

Although it is desirable to have the package substrate with TSPstructures larger than the semiconductor chip to increase the dutyratio, such as to be greater than 50%, the TSP structures occupy spaceand would undesirably increase the substrate area used to package thesemiconductor chip. In addition to increased package size, larger TSPareas also require more metal to gap fill the TSP structure and wouldincrease manufacturing cost. In some embodiments, the duty ratio is keptequal to or below than 65%.

In the discussion above, it was stressed that the duty ratio for apackage substrate for a semiconductor chip that release large amount ofheat, such as an LED chip, should be as high as possible. However,sometimes the duty ratio less than 50%, such as 20-30%, is sufficient todissipate heat generated by the semiconductor chip. In some embodiments,the duty ratio of the TSPs is equal to or greater than about 30%. Therequirement of duty ratio depends on the type of semiconductor chip tobe packaged.

As mentioned above, the semiconductor chip could an LED chip, inaccordance with some embodiments. An LED chip can include numerous LEDs.A single LED can generate red, yellow or blue light. To enablegenerating white light, three or multiple of three LEDs are needed.

The structures and patterns of TSPs described and shown above are merelyexamples, the shapes, patterns and arrangements of TSVs or TSPs that arenot mentioned here, or are variations of the structures mentioned aboveare also possible. The embodiments of through silicon plugs (TSPs) withdifferent patterns described above can be used under one or moresemiconductor chip(s) to improve heat dissipation and can be made withmanageable manufacturing concerns, such as long copper plating time andstructural strength.

The package substrates with through silicon plugs (or vias) describedabove provide lateral and vertical heat dissipation pathways forsemiconductor chips that require thermal management. Designs of throughsilicon plugs (TSPs) with high duty ratios can most effectively provideheat dissipation. TSP designs with patterns of double-sided combs canprovide high duty ratios, such as equal to or greater than 50%. Packagesubstrates with high duty ratios are useful for semiconductor chips thatgenerate large amount of heat. An example of such semiconductor chip isa light-emitting diode (LED) chip.

One aspect of this description relates to a method of making asemiconductor device. The method includes forming a first opening and asecond opening in a substrate. The method further includes forming aconductive material in the first opening and in the second opening, theconductive material comprising a joined portion where the conductivematerial in the first opening and the conductive material in the secondopening are electrically and thermally connected together at a firstsurface of the substrate. The method further includes reducing athickness of the substrate from a second surface of the substrate,opposite the first surface, to expose the conductive material in thefirst opening and the conductive material in the second opening. Themethod further includes connecting a device to the second surface of thesubstrate.

Another aspect of this description relates to a method of making asemiconductor device. The method includes etching a substrate to form afirst opening and a second opening and forming an isolation layer in thefirst opening and the second opening, the isolation layer having ahigher thermal resistance that the substrate. The method furtherincludes forming a conductive material in the first opening and in thesecond opening, wherein the isolation layer is located betweenconductive material and the substrate. The method further includesforming a metal pad over a first surface of the substrate, wherein themetal pad is electrically and thermally connected to the conductivematerial in the first opening and the conductive material in the secondopening. The method further includes bonding a device to the metal pad,wherein the metal pad is electrically and thermally connected to thedevice.

Various modifications, changes, and variations apparent to those ofskill in the art may be made in the arrangement, operation, and detailsof the methods and systems disclosed. Although the foregoing inventionhas been described in some detail for purposes of clarity ofunderstanding, it will be apparent that certain changes andmodifications may be practiced within the scope of the appended claims.Accordingly, the present embodiments are to be considered asillustrative and not restrictive, and the invention is not to be limitedto the details given herein, but may be modified within the scope andequivalents of the appended claims.

1. A method of making a semiconductor device, the method comprising:forming a first opening and a second opening in a first surface of asubstrate wherein a first region of the substrate having the firstsurface interposes the first and second openings; forming a conductivematerial in the first opening and in the second opening and over thefirst surface in the first region of the substrate; reducing a thicknessof the substrate from a second surface of the substrate, opposite thefirst surface, to a third surface opposite the first surface whichexposes the conductive material in the first opening and the conductivematerial in the second opening; and connecting a light emitting diode(LED) device to the third surface of the substrate.
 2. The method ofclaim 1, wherein the forming the conductive material further includesdepositing the conductive material in a third opening spaced a secondregion from the second opening, wherein the conductive material is notdisposed on a portion of the top surface of the second region.
 3. Themethod of claim 1, further comprising: forming an isolation layer in thefirst opening and in the second opening prior to forming the conductivematerial.
 4. The method of claim 1, further comprising: forming a gluelayer on the first conductive material nearest the first surface of thesubstrate.
 5. The method of claim 4, wherein the glue layer is disposeddirectly on the first conductive material.
 6. The method of claim 1,further comprising: forming a glue layer directly on the conductivematerial and on the portion of the top surface in the second region. 7.The method of claim 4, further comprising: attaching a second substrateusing the glue layer.
 8. A method of fabricating a semiconductor device,comprising: etching a first surface of a substrate to form a firstopening and a second opening, wherein the first opening is adouble-sided comb shape and the second opening is a double-sided combshape spaced a distance from the first opening; forming an isolationlayer in each of the first and openings; forming a conductive materialin the first and second openings; forming a metal layer on theconductive material in the first and second openings, wherein the metallayer extends laterally beyond the first and second openings; anddisposing a semiconductor chip on the metal layer.
 9. The method ofclaim 8, wherein the semiconductor chip is a light emitting diode (LED)chip.
 10. The method of claim 8, wherein the disposing the semiconductorchip includes disposing the semiconductor chip on the first and secondopening such that portions of the double-sided comb shape extend beyondan edge of the semiconductor chip.
 11. The method of claim 8, whereinthe forming the metal layer includes a plating a copper layer over thesubstrate and the conductive material.
 12. The method of claim 8,wherein the forming the isolation layer includes chemical vapordeposition forming a dielectric layer.
 13. The method of claim 8,further comprising: depositing a seed layer after the isolation layerand prior to the conductive material in the first and second openings.14. A method of making a semiconductor device, the method comprising:providing a substrate having a first surface and an opposing secondsurface; etching the first surface of a substrate to form a firstopening and a second opening; forming a conductive material in both ofthe first opening and the second opening, wherein each of the conductivematerial has a first end adjacent the first surface of the substrate anda second end opposing end, wherein the first end of the conductivematerial in the first opening is connected to the first end of theconductive material in the second opening by a portion of the conductivematerial that is disposed on the first surface of the substrate; forminga metal pad over the second surface of the substrate, wherein the metalpad is electrically connected to the conductive material in the firstopening and the conductive material in the second opening; and bonding adevice to the metal pad.
 15. The method of claim 14, wherein etching thesubstrate to form the first opening and the second opening comprisesforming the first opening as a circular shape and forming a secondopening as a ring shape surrounding and concentric with the firstopening.
 16. The method of claim 14, wherein etching the substrate toform the first opening and the second opening comprises forming twoadjacent double-sided comb shapes.
 17. The method of claim 14, whereinetching the substrate to form the first opening and the second openingcomprises forming two adjacent rectangular shape openings.
 18. Themethod of claim 14, wherein the forming the metal pad includes forming aseed layer directly on the second end of the conductive material in eachof the first and second openings.
 19. The method of claim 14, furthercomprising: etching a third opening in the first surface of thesubstrate; and forming the conductive material in the third opening,wherein the conductive material in the third opening is electricallyisolated from the conductive material in the first and second openings.20. The method of claim 14, further comprising: forming another metalpad on the conductive material in the third opening, wherein the metalpad is adjacent the second surface.